Glycerol Electro-Oxidation at Pt and Pt-Cu Catalysts on Carbon Fibres Prepared by a Potentiostatic Electrodeposition
Kanyapat Plub-in a
a Imperial College London, Department of Chemical Engineering, London SW7 2AZ, UK
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Fall 2023 Conference (MATSUSFall23)
#HOMHET - Bridging The Gap Between Homogeneous and Heterogeneous (Photo)-Electrocatalysis
Torremolinos, Spain, 2023 October 16th - 20th
Organizers: Idan Hod, Elena Mas Marzá and Menny Shalom
Poster, Kanyapat Plub-in, 341
Publication date: 18th July 2023

Hydrogen generated electrochemically by a water electrolysis cell in an ion exchange membrane configuration is regarded as a clean energy technology. However, the large fraction for the total electrical energy that is used for the anodic oxygen evolution reaction (OER) to produce low-price oxygen hinders the industrial-scale production of hydrogen. Electrocatalytic glycerol oxidation (GEOR) is a promising alternative to simultaneously produce value-added products and hydrogen. Platinum is currently one of the most active catalysts for GEOR due to its ability to break the C-H bond, but its performance suffers from various oxidation intermediates (CO-containing species) forming during GEOR and strongly adsorbing on Pt active sites. Pt-based bimetallic catalysts, therefore, have been increasingly studied to improve CO tolerance. In this work, Pt and Pt-Cu catalysts were proposed and synthesised by one-step potentiostatic electrodeposition onto a carbon fibre cloth (CFC) used as a gas diffusion layer for integrating in a membrane electrode assembly electrolysis cell. The surface morphology and composition of both depositions on carbon fibre were observed by scanning electron microscopy and energy dispersive spectroscopy. The electrocatalytic performance of both materials towards GEOR in 1 M NaOH was evaluated by cyclic voltammetry (with and without added glycerol) and chronoamperometry. It was observed that the electrocatalytic activity of the Pt-Cu/CFC at a content of ca. 37.5 wt% Pt was superior to that of Pt/CFC in terms of lower GEOR onset potential, higher mass activities and current density. The Pt-Cu/CFC also exhibited less CO(ads) poisoning than the Pt/CFC during long-term electrolysis. This improvement could be attributed to the presence of Cu atoms increasing the formation of oxygenated species which facilitate the oxidation of adsorbed intermediates on the Pt active sites.

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