Open-shell conjugated small molecules and polymers for optoelectronics
Hugo Bronstein a
a University of Cambridge, Yusuf Hamied Department of Chemistry, Lensfield Road, Cambridge, United Kingdom
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Fall 2023 Conference (MATSUSFall23)
#ELMOL - The future of molecular electronics
Torremolinos, Spain, 2023 October 16th - 20th
Organizer: Rachel Kilbride
Invited Speaker, Hugo Bronstein, presentation 321
DOI: https://doi.org/10.29363/nanoge.matsus.2023.321
Publication date: 18th July 2023

Optoelectronics devices based on closed-shell organic small molecules and polymers have proven themselves as disruptive technology in display applications. Their ability to interchange light absorption or emission with electrical generation or excitation has allowed for the development of organic light emitting diodes (OLED), organic photovoltaics (OPV) and other devices with commercially relevant performance and costs. However, the fundamental electronic structure of these closed-shell materials imposes limitations on their use. The excitonic nature of these materials means that for every bright, optically accessible (singlet) state there is a corresponding dark (triplet) state at a lower energy. The presence of dark triplet states is the cause for both the lower efficiency and lower stability in current generation organic optoelectronic devices relative to their inorganic counterparts. We propose to generate an entirely new set of optoelectronic materials based on open-shell (radical) organic materials where the lowest energetically excited state is an optically bright state, thus eliminating the major loss mechanism in current organic optoelectronic devices. In addition, the proposed materials can have high-spin which can be optically (or otherwise) manipulated opening up the possibility of using organic materials in next generation quantum technologies.

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