Mechanistic insights on solid electrolyte interface (SEI) formation in sodium ion batteries
Sarat Alabidun a, Bethan J. V. Davies b, Maria Crespo-Ribadeynera c, Mary P. Ryan b, Ifan E.L. Stephens b, Magda Titirici a
a Imperial College London, Department of Chemical Engineering, London SW7 2AZ, UK
b Department of Materials, Imperial College London, Exhibition Road, SW7 2AZ London, United Kingdom
c Queen Mary University of London,School of Engineering and Material Sciences
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Fall 2023 Conference (MATSUSFall23)
#EMERBAT - Emerging battery technologies
Torremolinos, Spain, 2023 October 16th - 20th
Organizers: Philipp Adelhelm, Maria Crespo and Guiomar Hernández
Poster, Sarat Alabidun, 301
Publication date: 18th July 2023

The solid electrolyte interface (SEI) in sodium batteries influence the long-term performance and eventual degradation of the cell, hence an in depth understanding of their formation mechanism is important. This would aid better cell and electrolyte design to allow for longer lasting battery life and slower degradation.

According to current research, the solid electrolyte interface layer is a passivation layer formed on the surface of the anode during the first few charge-discharge cycles due to decomposition of the electrolyte. This decomposition is triggered by the difference in redox potential between the electrodes and the electrolyte.(1) Beyond this explanation, the SEI formation mechanism is still poorly understood, particularly with respect to the chemical reactions and species that are involved in its formation.

In this research we study SEI formation using electrochemical mass-spectrometry, to determine the gases evolved during the process. In addition, we utilise the time of flight secondary ion mass spectrometry technique (TOFSIMS) which is surface sensitive, to investigate the SEI components on the anode surface. Finally, we conduct electrochemical characterisation including electrochemical impedance spectroscopy, galvanostatic cycling and cyclic voltammetry, to give further insights into the relationship between SEI and electrochemical performance.

 

 

 

I would like to acknowledge the Damians Cummins Scholarship for providing PhD funding

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