Proceedings of MATSUS Fall 2023 Conference (MATSUSFall23)
DOI: https://doi.org/10.29363/nanoge.matsus.2023.146
Publication date: 18th July 2023
The wide variations in bandgaps offered by metal halide perovskites provide a unique opportunity to develop multijunction thin-film solar cells with an efficiency that surpass the limits of a single-absorber photovoltaic devices. Additionally, perovskite-based multijunction solar cells enable lower the levelized cost of energy. Recent results on perovskite-perovskite and perovskite-copper indium gallium selenide (CIGS) multijunction cells will be presented. Often wide-bandgap mixed-halide perovskites and narrow-bandgap mixed-metal perovskites suffer from non-radiative recombination due to bulk traps and interfacial recombination centers that limit the open-circuit voltage in wide-bandgap sub-cells and restrict photocurrent for narrow-bandgap materials. We studied the origin of these traps with photocurrent spectroscopy and absolute photoluminescence spectroscopy and employ passivation strategies to eliminate losses and increase stability. Combined with reducing parasitic absorption losses using optical simulations as guide, this allows fabricating efficient multi-junction cells in all-perovskite configurations and in combination with other thin-film semiconductors such as CIGS. Collectively, these strategies enable monolithic tandem solar cells with a power-conversion efficiency of 26%.