Iridium-free anodes for acidic water electrolysis
Alexandr Simonov a, Darcy Simondson a, Mohamed Elghafar a, Manjunath Chatti a, Sibimol Luke a, Ioannis Spanos b, Marc Tesch b
a School of Chemistry, Monash University, Victoria 3800, Australia
b Max Plank Institute for Chemical Energy Conversion, 45470, Mülheim an der Ruhr, Germany
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Fall 2023 Conference (MATSUSFall23)
#WATERCAT - Experiment and theory in the catalysis of water electrolysis and hydrogen fuel cells
Torremolinos, Spain, 2023 October 16th - 20th
Organizers: Serhiy Cherevko and Nejc Hodnik
Invited Speaker, Alexandr Simonov, presentation 102
DOI: https://doi.org/10.29363/nanoge.matsus.2023.102
Publication date: 18th July 2023

Water electrolysers (WE) with proton-conducting electrolytes, especially those based on the polymer electrolyte membranes (PEM), present many important technological advantages over the traditional alkaline-based electrolyte systems. On a negative side, efficient and practically robust operation of the PEMWEs is challenging to achieve without the use of the oxygen evolution reaction (OER) catalysts based iridium, typically introduced to the anodes at mg cm-2 levels of loading. The key limitation here is not just the very high cost of Ir, but also the availability of this very scarce metal that is mined on a scale of only few tonnes per annum.

Aiming to resolve this challenge, our work has focused on the development of iridium-free OER catalysts capable of robust operation at low pH and elevated temperatures on an extended timescale. Towards this aim, we have implemented a “catalyst-in-matrix” design concept, which is based on combining the catalytically active oxide species, e.g. cobalt or manganese, with an electrically conductive matrix that is thermodynamically stable under the target operating conditions, e.g. oxides of lead and antimony. The talk will present several examples of such systems based on various “catalyst” and “matrix” elements, with a specific focus on the durability of the materials in operation. Integration of some of the most promising catalyst, including those operating in a self-healing mode, into the anodes of the devices for the low-pH water electrolysis will be highlighted.

The financial support from the Australian Research Council (project FT200100317), Australian Renewable Energy Agency (project 2018/RND008) is gratefully acknowledged. Parts of the work were undertaken at the XAS beamline of the Australian Synchrotron, LiXEdrom beamline of the BESSY II synchrotron facility, Monash Centre for Electron Microscopy and Monash X-ray platform.

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