Oxide and halide perovskite photoelectrochemical and photocatalytic materials for solar fuels
Salvador Eslava a
a Department of Chemical Engineering and Centre for Processable Electronics, Imperial College London, London SW7 2AZ, UK
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Fall 2023 Conference (MATSUSFall23)
#HOMHET - Bridging The Gap Between Homogeneous and Heterogeneous (Photo)-Electrocatalysis
Torremolinos, Spain, 2023 October 16th - 20th
Organizers: Idan Hod, Elena Mas Marzá and Menny Shalom
Invited Speaker, Salvador Eslava, presentation 066
DOI: https://doi.org/10.29363/nanoge.matsus.2023.066
Publication date: 18th July 2023

Photoelectrochemical and photocatalytic conversion of water and carbon dioxide using solar energy offers a clean solution to the world energy requirements of a sustainable future. Achieving its full potential depends on developing inexpensive photoelectrodes and photocatalysts that can efficiently absorb solar light and drive the photoinduced charges to react with water and carbon dioxide. In this talk, I will present recent developments we have achieved in the group in the preparation of inexpensive photoanodes, photocathodes and photocatalyst composites. For example, we have achieved nanostructured BiVO4 functionalized with bismuthene and NiFeOx that influence surface states and boost 6 times their photocurrent performance, as well as BiVO4 with Ni and Co phosphide co-catalysts that offer a useful series of samples to understand semiconductor-electrocatalyst synergies. We have also achieved halide perovskites CsPbBr3 photoanodes protected with printed carbon layers and graphite sheets and functionalized with NiFeOx water-oxidation electrocatalyst, achieving photoanodes of low onset potential of +0.4 V vs. RHE and photocurrents around 8 mA cm-2 at 1.23 V vs. RHE for water oxidation. These, moreover, achieve operational stabilities for oxygen evolution above 100 h, inexpensively extended to weeks by replacement of the graphite protection. We will also briefly present photocathodes made of oxide perovskites and composites of halide perovskites, such as Cs2AgBiBr3/bismuthene and Cs3Bi2Br9/g-C3N4, for their use in the photocatalytic reduction of CO2. An extended characterization helps us relate their physical and charge-transfer properties to their performance, guiding us in their rational design for their optimization and future application.

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