Metal oxide shells for quantum dots by colloidal atomic layer deposition
Anna Loiudice a, Ona Lecina-Segura a, Raffaella Buonsanti a
a EPFL École Polytechnique Fédérale de Lausanne, Laboratory of Nanochemistry for Energy, Department of Chemical Science and Engineering, Switzerland, Sion, Switzerland
Proceedings of Internet NanoGe Conference on Nanocrystals (iNCNC)
Online, Spain, 2021 June 28th - July 2nd
Organizers: Maksym Kovalenko, Maria Ibáñez, Peter Reiss and Quinten Akkerman
Oral, Anna Loiudice, presentation 030
DOI: https://doi.org/10.29363/nanoge.incnc.2021.030
Publication date: 8th June 2021

Quantum dots have emerged as technologically relevant materials for efficient optoelectronic devices, such as LED televisions and solar cells. However, they are often unstable as thin films or as inks in the environment or during their processing.

In this talk, I will discuss how oxide shells can help to overcome such issues. I will focus on our recently developed colloidal atomic layer deposition (c-ALD) approach to grow tunable alumina shells around quantum dots.[1] I will briefly compare the c-ALD with the previously developed gas-phase ALD in film.[2] This newly developed synthesis has the advantage of preserving the colloidal stability of the nanocrystalline core while controlling the shell thickness from 1 to 6 nm.[1] I will describe the details on how the aluminum precursor interacts with the surface of the QDs during the nucleation step and how the shell eventually grows. Finally, I will also discuss some of our recent founding on the impact of a thin metal oxide shell on the dynamicity of the quantum dots ligands.

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