Advances in kinetics processes of halide perovskite solar cells by neuron-style nonlinear model equations and electrooptical techniques
Juan Bisquert a
a Institute of Advanced Materials (INAM), Universitat Jaume I, Castellón, Spain.
Proceedings of Workshop on Stable Hybrid Perovskite Materials for Photovoltaics Under Real-World Conditions (StabPeroWorkshop)
Fribourg, Switzerland, 2023 February 23rd - 23rd
Organizers: Jovana Milic and Daniel Ramirez
Invited Speaker, Juan Bisquert, presentation 003
DOI: https://doi.org/10.29363/nanoge.stabperoworkshop.2023.003
Publication date: 20th January 2023

The dynamic response of metal halide perovskite devices shows a variety of physical responses that need to be understood and classified for enhancing the performance and stability and for identifying physical behaviours that may lead to developing new applications. Beyond the well-established characteristics of regular impedance arcs, we address the appearance of inductor effect at high voltage in perovskite solar cell. We present a physical model in terms of delayed recombination current that explains the evolution of impedance spectra and the evolution of current-voltage curves. A multitude of chemical, biological, and material systems present an inductive behavior that is not electromagnetic in origin. Here, it is termed a chemical inductor. We show that the structure of the chemical inductor consists of a two-dimensional system that couples a fast conduction mode and a slowing down element. Therefore, it is generally defined in dynamical terms rather than by a specific physicochemical mechanism. The impedance spectra announce the type of hysteresis, either regular for capacitive response or inverted hysteresis for inductive response. We address the characterization of electron diffusion and radiative emission in halide perovskites using a range of light stimulated techniques as IMPS, IMVS, and voltage controlled light emission technique (LEVS).

We thank MICINN  for support by the project EUR2022-134045/ AEI / 10.13039/501100011033.

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info