Solution deposition-conversion of perovskite solar cells
Pablo Docampo a
Oral, Pablo Docampo, presentation 058
Publication date: 1st July 2014

Solar cells based on alkyl ammonium halogen plumbate perovskites have recently garnered a large amount of interest in the photovoltaics community. Previously reported record-breaking devices incorporate a solution processed planar heterojunction with the MAPbI3 sandwiched between n and p-type charge collection layers. Here, the focus will be on the fabrication protocols developed for the deposition of planar heterojunction solar cells via a solution deposition-conversion technique on TiO2 coated FTO substrates and with state-of-the-art Spiro-OMeTAD as the hole transporter.  Our results show that the processing conditions of the conversion solution have a deep influence on the resulting perovskite structures, from extended charge diffusion lengths to other morphological effects. We have studied the prepared structures not only via structural analysis, but also through time-resolved photoluminescence measurements. In this way we have pinpointed the origin of the limits to power conversion efficiency, mainly short diffusion lengths of the photoexcited species.  By tuning the deposition conditions, we have obtained solar cells exhibiting power conversion efficiencies of up to 15% for the typical MAPbI3 perovskite and approaching 7% for wide bandgap perovskite absorbers.



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