Publication date: 1st July 2014
Within the last few years, lead-based organo-metal halide perovskite solar cells have become the biggest contenders in the drive to provide a cheap, clean, renewable source of energy, rapidly climbing to efficiencies of over 16%. One of the biggest concerns about the use of this material is the toxicity of lead, prompting researchers to search for a lead free alternative. One of the most obvious alternatives to lead is tin, which like lead, is also a group 14 metal. However, the stability of tin in its 2+ oxidation state has proved to be an overwhelming challenge. In this work we have synthesised and characterised the tin perovskite CH3NH3SnI3 by encapsulating it under inert atmosphere. This material shows an absorption onset at approximately 1000nm, and photoluminescence at 950 nm corresponding to a band gap of approximately 1.25 eV. Here we report the first completely lead-free, CH3NH3SnI3 perovskite solar cell, reaching efficiencies of >6% under 1 sun illumination. Remarkably, we achieve voltages of up to 0.9V, suggesting that this material has intrinsically low voltage losses as compared to its lead analogue and even crystalline silicon. Further investigation and complete stabilisation of this material should allow a much greater increase in performance leading to efficiencies of >20%.