Publication date: 1st July 2014
Nanoparticles of cadmium selenide (CdSe) and sulfide (CdS) have being showed as good electron acceptors for hybrid solar cells. They can be prepared from aqueous solutions with cadmium, selenium or sulfur sources, sodium citrate as cadmium ion complex agent and an alkaline solution to adjust the pH value. It is observed that the reaction kinetics of CdSe and CdS depend both on the hydroxide source (NH4OH or KOH) and pH values. CdSe precipitated more at lower pH value and CdS, at higher one. These phenomena were carefully used to achieve the formation of core/shell particles of CdSe and CdS in one-step solution process with either of two as core or shell. The appropriate pH values have been selected at each stage of synthesis for each alkaline source. X-ray diffraction patterns, diffuse optical reflectance spectra and scanning electron micrographs of the core/shell products were analyzed. Photovoltaic performance of heterojunctions with core/shell particles and poly(3-hexylthiophene) (P3HT) was studied and compared with that of CdSe- or CdS-P3HT. The hydroxide source used for CdSe and CdS formation influenced on the photovoltaic parameters of the corresponding solar cells. It is concluded that very thin layer or shell of CdS was formed on CdSe core with either of two alkaline sources at pH 10-11. The formation of CdSe shell on CdS core, on the other hand, was possible only in selenium shell solution with pH lower than 9.