OPTIMIZATION of COMPOSITE ELECTRODES with CARBON MESOPOROUS MATERIAL and FUNCTIONAL MATERIALS for ENHANCED SUPERCAPACITOR PERFORMANCE
Chelliah Koventhan a b, Ching-Hung Kuo a, An-Ya Lo a b
a Institute of Electro-Optical Engineering, National Taiwan Normal University, Taipei, Taiwan
b Department of Chemical and Materials Engineering, National Chin-Yi University of Technology, Taichung, Taiwan
Proceedings of 24th International Conference on Solid State Ionics (SSI24)
Emerging Materials for High-Performance Devices
London, United Kingdom, 2024 July 14th - 19th
Organizers: John Kilner and Stephen Skinner
Poster, An-Ya Lo, 618
Publication date: 10th April 2024

The pursuit of electrode materials with excellent electrochemical properties is critical to improving the performance of batteries and supercapacitors. Here, we report on our recent research progress and ongoing research on supercapacitors. By using a carbon mesoporous material (CMK-3, specific surface area = 1340 m2/g) as the matrix of the composite electrode, electrodes usually perform high power density because of the presence of the double-layer capacitance (EDLC). Integrated with functional material, it enables further adjustment of the properties toward the desired aspects. For example, we improve the energy density of CMK-3-based electrode under high-power operation mode with improved cyclic stability through the dispersion of SiO2 nanospheres on it [1]; hybrid with faradaic active polyaniline (PANi) and hydroquinone (HQ), we developed a PANi/CMK-3/HQ composite system with excellent cyclic stability and high specific capacitance [2]. On the other hand, we recently developed a novel design of manganese molybdate@nickel molybdate (MnMoO4@NiMoO4) nanorods-on-nanosheets core-shell structures [3]. This binder-free electrode demonstrates superior specific capacitance, energy density, power density, and cycling stability. Combining the abovementioned ideas, we are now developing a core-shell structure by using CMK-3 as the core and SmVO4 as the shell, and we expect this study to contribute to the development of innovative electrode materials for high-efficient supercapacitors.

The authors acknowledge the financial support provided by the National Science and Technology Council (Grant Nos. 111-2221-E-167-018-MY3; 111-2221-E-167-008-MY3), Taiwan. The authors thank the BET, XRD, TPD, and SEM measurement services provided by the Green Energy and Engineering Materials Research Center of the National Chin-Yi University of Technology (NCUT), Taiwan.

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