Investigation of Thermo-mechanical Stability in High Temperature Solid Oxide Electrochemical Cell
Soomin Choi a, Janghyun Lim b, Gyeong Duk Nam a, Gahyeon Lee a f, Young-il Kown c, Hyeon Jin Lee a, John T.S. Irvine d, Tae Ho Shin e, Jongsup Hong b, Jong Hoon Joo a f
a Gwangju institute of science and technology, 123 Cheomdangwagi-ro, Buk-gu, gwangju, Korea, Republic of
b Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul, 120, Korea, Republic of
c Korea Electric Power Corporation, South Korea
d University of St Andrews, Physics and Astronomy, St Andrews, United Kingdom
e Korea Institute of Ceramic Engineering & Technology, 101 Soho-ro, Jinju-si, Gyeongsangnam-do, Korea, Republic of
f Research Center for Innovative Energy and Carbon Optimized Synthesis for Chemicals
Proceedings of 24th International Conference on Solid State Ionics (SSI24)
Fundamentals: Experiment and simulation
London, United Kingdom, 2024 July 14th - 19th
Organizers: John Kilner and Stephen Skinner
Oral, Soomin Choi, presentation 347
Publication date: 10th April 2024

A solid oxide fuel cell (SOFC), an eco-friendly energy conversion device, has gained significant attention as a power generator due to its high fuel flexibility and efficiency and low emissions of pollutants. However, SOFC has inherently poor thermomechanical stability, ascribed to ceramic properties, such as high elastic modulus and low thermal conductivity. Therefore, it is prone to crack formation and failure of the cell in the thermal shock caused by rapid temperature changes, leading to slow start-up/shutdown and unstable operation under thermal cycling. To achieve exceptional thermomechanical strength, an innovative design of the solid oxide cell is indispensable, thereby overcoming the inherent vulnerability of ceramics to thermal shock.

This study examines the temperature and stress distribution in a solid oxide cell exposed to rapid heating conditions via computational simulation. Thermal stress analyses were employed to assess the thermomechanical robustness of anode-supported and electrolyte-supported SOFCs. Critical vulnerabilities within each SOFC configuration were identified, providing essential insights into their respective thermomechanical stabilities.

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