Electrochemical Characteristics of Metal Supported Solid Oxide Fuel Cells with a Buffer Layer Fabricated Using Ultrafine GDC Particles
Sang Eun Lee a, Preethi Sudarsan a, Hee Jung Park a
a Dankook University, 119 Dandae-ro, Dongnam-gu, Cheonan, Korea, Republic of
Proceedings of 24th International Conference on Solid State Ionics (SSI24)
Emerging Materials for High-Performance Devices
London, United Kingdom, 2024 July 14th - 19th
Organizers: John Kilner and Stephen Skinner
Oral, Sang Eun Lee, presentation 330
Publication date: 10th April 2024

In this research, we address the critical challenge of fabricating a thin and dense Gd-doped ceria (GDC) buffer layer to impede interfacial elemental diffusion between the yttrium-doped zirconia electrolyte and the perovskite functional cathode within metal supported solid oxide fuel cell (MS-SOFC). To overcome the limitations of conventional sintering processes (>1400 ºC), we successfully synthesized GDC particles with a precise size of 3 nm using a novel precipitation method. The subsequent application of a spin-coating process enabled the formation of a thin (<1 μm) buffer layer at temperatures below 1000 ºC. Microstructure analysis at varying temperatures confirmed the efficacy of the synthesized buffer layers. These advancements were applied to a cutting-edge MS-SOFC, manufactured through co-firing in a reducing atmosphere. Electrochemical investigations, employing 2-probe AC impedance and DC measurements, highlighted the superior performance achieved through the optimization of microstructure in each layer and the incorporation of a thin ceria-blocking layer. This study presents a groundbreaking approach to enhance the efficiency and feasibility of MS-SOFC, emphasizing the significance of dense GDC buffer layer at low temperature and its application in next-generation metal-supported fuel cell technologies.

 

This work was supported by the National Research Foundation of Korea(NRF) grant funded by the Korea government(MSIT) (No. RS-2023-00236572).

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