Publication date: 10th April 2024
In this research, we address the critical challenge of fabricating a thin and dense Gd-doped ceria (GDC) buffer layer to impede interfacial elemental diffusion between the yttrium-doped zirconia electrolyte and the perovskite functional cathode within metal supported solid oxide fuel cell (MS-SOFC). To overcome the limitations of conventional sintering processes (>1400 ºC), we successfully synthesized GDC particles with a precise size of 3 nm using a novel precipitation method. The subsequent application of a spin-coating process enabled the formation of a thin (<1 μm) buffer layer at temperatures below 1000 ºC. Microstructure analysis at varying temperatures confirmed the efficacy of the synthesized buffer layers. These advancements were applied to a cutting-edge MS-SOFC, manufactured through co-firing in a reducing atmosphere. Electrochemical investigations, employing 2-probe AC impedance and DC measurements, highlighted the superior performance achieved through the optimization of microstructure in each layer and the incorporation of a thin ceria-blocking layer. This study presents a groundbreaking approach to enhance the efficiency and feasibility of MS-SOFC, emphasizing the significance of dense GDC buffer layer at low temperature and its application in next-generation metal-supported fuel cell technologies.
This work was supported by the National Research Foundation of Korea(NRF) grant funded by the Korea government(MSIT) (No. RS-2023-00236572).