Beyond Li: Na, K and Al based batteries-progress, challenges and prospects
Magda Titirici a
a Department of Chemical Engineering, Imperial College London, London, SW7 2AZ, UK
Proceedings of 24th International Conference on Solid State Ionics (SSI24)
Devices for a Net Zero World
London, United Kingdom, 2024 July 14th - 19th
Organizers: John Kilner and Stephen Skinner
Keynote, Magda Titirici, presentation 319
Publication date: 10th April 2024

To mitigate the climate change and reach a carbon neutral society before it is too late, a mix of sustainable energy technologies are needed.

Batteries will continue to play a vital role in decarbonising transportation as well as in storing the intermittent renewable energy. Li ion batteries have revolutionised the electrification of transportation and contributed significantly to grid storage. However, there are increasing concerns with the availability of the minerals currently used in Li-ion batteries today, especially looking at the predicted growth of batteries demand. Diversification of battery technologies with more sustainable options in mind, not only for the raw minerals used in future batteries but also for more sustainable manufacturing practices for cells and packs are needed.

In my talk I will touch on some of these sustainable practices needed to be implemented today while showing the 12 principles of “green batteries” inspired from “green chemistry” my research group introduced. I will than focus on Na-ion batteries, the next battery technology in line for commercialisation in 2024, with emphasis on our research on hard carbon anodes on understanding the fundamentals on Na ion storage using a mix of characterisation techniques coupled with electrochemistry. I will also discuss the importance and complexity of solid electrolyte interfaces and some perspectives on commercialisation from our group.

I will also resent some new insights onto a very old research topic: intercalation of alkali metals into graphite. We have performed in depth study on K intercalation in graphite using a combination of Raman (including looking at the low frequency band), XRD, dilatometry, optical microscopy as well as DFT calculation which when coupled with electrochemistry and post-mortem TOF-SIMS reveal the formation of a solid electrolyte interface responsible for capacity loss in the first cycles.

I will present also on Al-ionic liquid-graphite dual ion batteriey configurations while focusing on the Al anode corrosion and degradation using XPS, XAFS and post-mortem microscopy after various cycles as well as understanding the intercalation of AlCl4- in graphite, soft and hard carbon and the difference in the storage mechanism among such classes of carbons.

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