Why battery electrodes never seem to yield reliable GITT measurements
Stephen Dongmin Kang a
a Department of Materials Science & Engineering, Seoul National University, Seoul, Korea
Proceedings of 24th International Conference on Solid State Ionics (SSI24)
Fundamentals: Experiment and simulation
London, United Kingdom, 2024 July 14th - 19th
Organizers: John Kilner and Stephen Skinner
Oral, Stephen Dongmin Kang, presentation 294
Publication date: 10th April 2024

One of the most widely used electroanalytical methods for understanding the kinetics of composite battery electrodes is GITT – the Galvanostatic Intermittent Titration Technique [1,2]. At the same time, it is common for battery researchers to question the reliability of GITT measurements. The level of skepticism associated with GITT varies; some question its quantitative accuracy (but not much on otherwise trends), whereas others raise more serious questions on its relevancy for kinetics. The root causes for the unreliability of GITT are also perceived quite differently among researchers. Some believe that the unreliability is a result of poor implementation of the technique, implying that careful measurements could produce reliable results. Others believe that there are more fundamental limitations, dismissing any kinetic information obtained from GITT measurements. In this talk, we will isolate the implementation issues and focus on answering the question: "if the measurement protocol is optimized, can we extract relevant kinetic parameters from GITT measurements on composite battery electrodes?" We will take lessons from recent microscopic kinetics studies [3-7] and understand their implications from the perspective of using electroanalytical techniques such as GITT.

This work was supported by the National Research Foundation of Korea.

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