Publication date: 10th April 2024
BaFeO3-d is a prototypical triple-conducting oxide with mobile protons, oxygen vacancies, and electron holes. Such materials are key components for protonic ceramic fuel/electrolysis cells and hydrogen permeation membranes.
BaFeO3-d can be doped with various redox-inactive cations in the perovskite's B-site, which typically increases the proton uptake.[1,2] This effect is attributed to the introduction of local lattice distortions (Fe-O-Fe buckling) that decrease the covalency of the Fe-O bonds.[3,4]
In the present poster, the variation of proton uptake with size and concentration of dopants such as Acc = Sc3+, Y3+, In3+, Zr4+, Ce4+, Sn4+ - covering a large range of ion radius and acid/base properties - is investigated using thermogravimetry. Dopants with size mismatch below 0.1 Å can be introduced in large concentration and form extended solid solutions, while the solubility of dopants with larger mismatch does not exceed 20%. The optimum dopant size and concentration for maximizing proton uptake while preserving a high electronic conductivity is discussed.
nanoGe is a prestigious brand of successful science conferences that are developed along the year in different areas of the world since 2009. Our worldwide conferences cover cutting-edge materials topics like perovskite solar cells, photovoltaics, optoelectronics, solar fuel conversion, surface science, catalysis and two-dimensional materials, among many others.
Previously nanoGe Spring Meeting (NSM) and nanoGe Fall Meeting (NFM), MATSUS is a multiple symposia conference focused on a broad set of topics of advanced materials preparation, their fundamental properties, and their applications, in fields such as renewable energy, photovoltaics, lighting, semiconductor quantum dots, 2-D materials synthesis, charge carriers dynamics, microscopy and spectroscopy semiconductors fundamentals, etc.
International Conference on Hybrid and Organic Photovoltaics
International Conference on Hybrid and Organic Photovoltaics (HOPV) is celebrated yearly in May. The main topics are the development, function and modeling of materials and devices for hybrid and organic solar cells. The field is now dominated by perovskite solar cells but also other hybrid technologies, as organic solar cells, quantum dot solar cells, and dye-sensitized solar cells and their integration into devices for photoelectrochemical solar fuel production.
Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics
The main topics of the Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics (IPEROP) are discussed every year in Asia-Pacific for gathering the recent advances in the fields of material preparation, modeling and fabrication of perovskite and hybrid and organic materials. Photovoltaic devices are analyzed from fundamental physics and materials properties to a broad set of applications. The conference also covers the developments of perovskite optoelectronics, including light-emitting diodes, lasers, optical devices, nanophotonics, nonlinear optical properties, colloidal nanostructures, photophysics and light-matter coupling.
The International Conference on Perovskite Thin Film Photovoltaics Perovskite Photonics and Optoelectronics (NIPHO) is the best place to hear the latest developments in perovskite solar cells as well as on recent advances in the fields of perovskite light-emitting diodes, lasers, optical devices, nanophotonics, nonlinear optical properties, colloidal nanostructures, photophysics and light-matter coupling.