Proceedings of Online school on Fundamentals of Semiconductive Quantum Dots (QDsSCHOOL)
DOI: https://doi.org/10.29363/nanoge.qdsschool.2021.001
Publication date: 30th April 2021
An innovative sequential eco-friendly spray coating (SEF-SC) technique is developed to uniformly deposit metal halide perovskite films on macro-scale textured surfaces, such as textured crystalline-silicon wafers. Contrasting with previous work on spray-coated perovskite solar cells, our method completely avoids the use of toxic and dangerous solvents. Both MAPbI3 and CsFAMAPbI3-xBrx perovskite films deposited by SEF-SC show excellent optoelectronic properties and no phase segregation, even when synthesized in ambient conditions. We obtain uniform perovskite coatings on textured-silicon heterojunction solar cells showing the promise of this method, which holds the potential for scalable wet processing of perovskites on rough substrates, such as for low-cost perovskite/silicon tandem solar cell fabrication.