Publication date: 2nd November 2020
Perovskite materials are on the way to commercialization as photoactive component of optoelectronic devices, especially photovoltaic and light-emitting diodes. Perovskite materials need to be adopted to industrial deposition methods for spreading in commercial semiconductors devices. In this work we experimentally demonstrated formation of highly luminescence perovskite materials by single step CVD deposition approach. Evaporated materials were prepared by dry mechanochemical synthesis at room temperature. Milled products were used as evaporation materials and deposited on glass substrates. The variety of CsPb2Br5, CsPbBr3 and Cs4PbBr6 phase compositions were synthesized in a single step CVD process. Powders and films properties were determined as a result of comparative study (PL, XRD, EDX). Vacuum deposition allows to uniform film formation on top of texturized morphology substrates for multijunction solar cells.
Authors gratefully acknowledge the financial support from the Ministry of Science and Higher Education of the Russian Federation in the framework of MegaGrant (no. 075-15-2019-872 /074-02-2018-327).