Thermal Annealing Effect on the Performance of Polymer : Non-Fullerene-based Solar Cells using V2O5 as HTL
Jose G. Sanchez a, Alfonsina Abat Amelenan Torimtubun a, Victor S. Balderrama b, Magali Estrada c, Josep Pallares a, Lluis F. Marsal a
a Department of Electronic, Electric and Automatic Engineering, Universitat Rovira I Virgili, 43007 Tarragona, Spain
b Catedra-CONACYT, Microtecnologias, Centro de Ingenieria y Desarollo Industrial, 76125 Santiago de Queretaro, Mexico
c Seccion de Electronica del Estado Solido, Departamento de Ingenieria Electrica, CINVESTAV, 07360 Mexico City, Mexico
Materials for Sustainable Development Conference (MATSUS)
Proceedings of Online nanoGe Fall Meeting 20 (OnlineNFM20)
#NewOPV20. Non-fullerene Electron acceptors Within Organic Photovoltaics
Online, Spain, 2020 October 20th - 23rd
Organizers: Vida Engmann and Morten Madsen
Poster, Alfonsina Abat Amelenan Torimtubun, 240
Publication date: 4th October 2020
ePoster: 

The effects of thermal annealing on the photovoltaic properties of inverted polymer solar cells based on polymer donor PBDB-T and non-fullerene small molecule acceptor ITIC-M in the device structure of ITO/TiO2/PBDB-T:ITIC-M/V2O5/Ag are investigated. We found that device annealed at 100ºC showed the best performance under AM 1.5G illumination. The EQE and impedance spectra reveal that the highest EQE spectra of up to 80% and the lowest charge-transfer resistances were obtained by 100ºC-annealed device. These results indicate the importance of the thermal annealing on the charge-transfer at the active layer/vanadium oxide interface.

European Union's Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No. 713679; Spanish Ministerio de Ciencia, Innovación y Universidades (MICINN/FEDER) RTI2018-094040-B-I00; Agency for Management of University and Research Grants (AGAUR) ref. 2017-SGR-1527; Catalan Institution for Research and Advanced Studies (ICREA) under the ICREA Academia Award; CONACyT Project in Mexico under Grant 237213. The work of Víctor S. Balderrama was supported by the Project “Cátedras CONACYT Para Jóvenes Investigadores”.

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