Proceedings of Online International Conference on Hybrid and Organic Photovoltaics (OnlineHOPV20)
Publication date: 22nd May 2020
A distinctive feature of hybrid perovskite light-absorbing materials is the non-negligible ionic conductivity influencing photovoltaic performance and stability. Moving ions or vacancies can naturally accumulate at the outer interfaces (electrode polarization) upon biasing. Contrary to that approach, a modulation of conductive or recombination properties could manifest as an alteration in the low-frequency part of the impedance response, either producing inductive or large capacitive features. Under this last view, capacitances are not the response of polarized structures or charging mechanisms, but result from the modulation of currents. This work intends to provide evidences that assist us in distinguishing between these two dissimilar mechanisms, namely, real charge polarization and delayed current effects under bias in the dark. The analysis relays upon an experimental technique based on transient charging signals using the Sawyer-Tower circuit. Instead of applying an alternating small perturbation over a steady-state voltage (differential capacitance method), transient charging measures the resulting polarization upon large bias step under suppression of dc currents. Our findings reveal that real steady-state charge is indeed induced by the applied voltage in the dark, easily interpreted by means of charged real capacitors with values much larger than the film geometrical capacitance. The connection between that polarization and the charging of perovskite/contact interfaces is highlighted.
We acknowledge support from Horizon 2020 project (grant number 871336 - PEROXIS). M.G.-B. acknowledges Generalitat Valenciana for the grant GRISOLIAP/2018/073. SCIC at UJI are also acknowledged. O.A. acknowledges the financial support from the VDI/VD Innovation + Technik GmbH (Project-title: PV-ZUM) and the SAOT funded by the German Research Foundation (DFG) in the framework of the German excellence initiative. J.C. akcnowledges the partial support by project PUE-054-CONICET, Argentina.
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