Graphitic and Amorphous Nitrogen-Doped Carbon Nanodots as Additives for Perovskite Solar Cells
Silvia Collavini a, Francesco Amato b, Francesca Arcudi b c, Luka Đorđević b d, Ivet Kosta e, Maurizio Prato b f g, Juan Luis Delgado a g
a POLYMAT, University of the Basque Country UPV/EHU, ES, avenida tolosa 72,, San Sebastián, Spain
b Department of Chemical and Pharmaceutical Sciences, INSTM UdR, University of Trieste, Via Licio Giorgieri, 1, Trieste, Italy
c Department of Chemistry, Northwestern University, United States, Sheridan Road, 2145, Evanston, United States
d Simpson Querrey Institute, Northwestern University, US, East Superior Street, 303, Chicago, United States
e CIDETEC, Basque Research and Technology Alliance (BRTA), Donostia, ES, Paseo de Miramón, 196, San Sebastián, Spain
f CIC biomaGUNE, Donosti, ES, Paseo de Miramón, 182, San Sebastián, Spain
g IKERBASQUE, Basque Foundation for Science, ES, Bilbao, Spain
International Conference on Hybrid and Organic Photovoltaics
Proceedings of Online International Conference on Hybrid and Organic Photovoltaics (OnlineHOPV20)
Online, Spain, 2020 May 26th - 29th
Organizers: Tracey Clarke, James Durrant, Annamaria Petrozza and Trystan Watson
Poster, Silvia Collavini, 051
Publication date: 22nd May 2020
ePoster: 

Carbon dots (CDs) are nanoparticles with a carbon-rich core and, usually, a surface rich in functional groups such as carboxylic acids or amines. Their interesting properties, namely their absorption and fluorescence in the visible range, photo- and thermal stabilities, electrochemical properties and tuneable surface chemistry are some of the characteristics responsible for the high interest they have raised since their discovery. Some of these properties could also be beneficial for their use in combination with perovskite solar cells (PSCs). Although there are previous reports on carbon dots and PSCs being successfully combined, the general lack of understanding of useful CD properties is hampering even further progress. In this paper, we investigate the role of graphitic and amorphous nitrogen-doped carbon dots as additives for perovskite solar cells. The performances of the cells are evaluated, as well as the effect of the CDs on the stability of the devices. In each one of the considered cases, the introduction of a small amount of carbon dots was beneficial for the stability of the cells, and, under optimized conditions, their performances increased up to 109% of their initial performances after 40 days, while the reference’s dropped to 86%.

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