Proceedings of Online International Conference on Hybrid and Organic Photovoltaics (OnlineHOPV20)
Publication date: 22nd May 2020
The world of organic solar cells (OSC) have been taken by storm by the recent developments in non-fullerene acceptors (NFAs) with record efficiencies being published in close succession. However, not all polymers that previously performed well in fullerene based devices are suitable for use in a blend with NFAs. This seems to be especially the case for diketopyrrolopyrrole (DPP) based polymers and currently there is a lack of understanding as to why. In our research we aim to improve on solar cell performance of DPP-NFA blends and elucidate the reason behind their suboptimal performance in order to extend the range of useful polymers in high efficiency (near infra-red absorbing) NFA OSCs.
We fabricate solar cells from an active layer blend of PDPP5T:IEICO-4F and extensively analyze them using a range of spectral techniques (PL/EL/Abs/SubbandGap-EQE). Then we correct the recorded spectra for suppression or enhancement of the absorption or luminescence as a consequence of thin-film cavity effects. With these corrected spectra in hand, and with the help of morphological analysis tools like TEM/AFM/2D-GIWAXS, we aim to explain the change in device characteristics upon changing the solvent system.
Results regarding the efficiency look promising with over 50% EQE improvement using a ternary solvent system. This solvent system is comprised of chloroform and 1,8-diiodooctane with varying concentrations of chlorobenzene. Current results suggest that the addition of chlorobenzene to the mixture increased stacking efficiency in the IEICO-4F phase, which was reflected in 2D-GIWAXS and the (interference corrected) spectral data, and that this better packing has led to the increase in EQE and the decrease Voc.