Minimizing the Impact of Ion Movement in Perovskite-Based Image Sensors
Sergey Tsarev a b, Yulia Kominko a b, Kyuik Cho c, Lorenzo Ferraressi a b, Daria Pronyakova a b, Taekwang Jang c, Maksym Kovalenko a b, Yakunin Sergii a b
a ETH Zürich, Department of Chemistry and Applied Biosciences, Switzerland, Switzerland
b Empa-Swiss Federal Laboratories for Materials Science and Technology, CH-8600, Dübendorf, Switzerland
c Department of Information Technology and Electrical Engineering, ETH Zurich, Zurich, Switzerland.
Proceedings of Perovskite and Organic Semiconductors for Next-Generation Photodetectors and Space Application (NextPDs)
Dubrovnik, Croatia, 2024 June 10th - 11th
Organizers: Michele Sessolo, Beatrice Fraboni and Marisé Garcia-Batlle
Oral, Sergey Tsarev, presentation 005
Publication date: 19th April 2024

In this study, we examine the use of perovskite photodetectors as a potential replacement for silicon photodiodes in modern cameras. Perovskite photodetectors have high sensitivity to visible light and can be integrated into existing electronics, but their use in CMOS image sensors requires the application of reverse bias. Unfortunately, this leads to unstable detector performance due to ion migration effects. To address this issue, we propose using forward voltage pulses to attenuate ion migration effects while still capturing photoresponse under reverse bias. To demonstrate the feasibility of this approach, we present a proof-of-concept single-pixel readout system that simulates the operation of a real image sensor. We show that applying forward bias pulses after each integration frame allows for stable operation of perovskite photodetectors for over 180 hours, whereas constant reverse bias leads to degradation of detector performance within 10 minutes. Additionally, we demonstrate stable imaging using the read-out with alternating voltage pulses and 8x8 cross-bar arrays of perovskite photodetectors. Our readout scheme is an important step towards the development of highly sensitive perovskite image sensors and cameras that are resistant to ion migration effects.

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