Ultrathin gamma In2S3 nanoplatelets with atomically defined thickness and large aspect ratio
Lilian Guillemeney a, Laurent Lermusiaux a, Bruno Canut b, Benoit Mahler c, Benjamin Abécassis a
a Laboratoire de Chimie, CNRS, École Normale Supérieure de Lyon, 69007 Lyon
b Institut des Nanotechnologies de Lyon
c Institut Lumière Matière, UMR5306 - UCBL – CNRS 10 rue Ada Byron 69622 Villeurbanne CEDEX, France
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Spring Meeting 2022 (NSM22)
#SNI22. Semiconductor Nanocrystals I: Basic Science (synthesis, spectroscopy, electronic structure, device and application)
Online, Spain, 2022 March 7th - 11th
Organizers: Emmanuel Lhuillier, Sandrine Ithurria and Angshuman Nag
Contributed talk, Benjamin Abécassis, presentation 351
DOI: https://doi.org/10.29363/nanoge.nsm.2022.351
Publication date: 7th February 2022

Semi-conducting nanoplatelets (NPL) exhibit outstanding optical properties but contain toxic heavy metals such as cadmium, lead or mercury. Indium sulfide is believed to be a credible alternative for semi-conductor based applications. We report the synthesis of ultrathin indium sulfide In2S3 nanoplatelets which display a giant aspect ratio using a simple and fast solvothermal method. We show that these NPL display a thickness controlled at the atomic level below the nanometer, a width of around 9 nm and a length which can reach several micrometers. We determined the atomic composition of the inorganic core by Rutherford backscattering spectrometry (RBS) and measured by X-ray photoelectron spectrometry (XPS) an oleylamine surface coverage of 2.3 ligands per nm2. X-ray diffraction experiments and simulations as well as high-resolution dark-field STEM point towards a trigonal crystallographic structure (gamma phase). Depending on the dispersion solvent, these long ribbon-like nanoplatelets can form well dispersed colloids or bundles in which they stack face to face. Their large aspect ratio induces the formation of gels. Their lateral dimensions can be tuned by the amount of water present in the reaction media: anhydrous synthesis conditions lead to hexagonal nanoplates while controlled addition of water induces a symmetry break yielding long NPL with a rectangular

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