Proceedings of nanoGe Spring Meeting 2022 (NSM22)
DOI: https://doi.org/10.29363/nanoge.nsm.2022.279
Publication date: 7th February 2022
Organic solar cells (OSCs) using non-fullerene acceptors (NFAs) have garnered a lot of attention during the last years and showed dramatic increases in the power conversion efficiency (PCE). PCEs higher than 19% for single-junction systems were achieved, but these high-performance organic photovoltaic cells are often processed with halogenated solvents. To accelerate the mass fabrication of OSCs, green solvent processing is crucial to reduce the harmful effect of halogenated solvents to human health and our environment. In this talk, I will discuss the design, synthesis, and performance of organic semiconductors processed from green solvents such as xylene and 2-methyl tetrahydrofuran (2-MeTHF). 2-MeTHF can be obtained from furfural, which is derived from agricultural by-products. It fits within the class of solvents sought from renewable resources and the concept of capitalizing on waste to generate useful chemicals. Moreover, the toxicity of 2-MeTHF is lower than that of commonly used halogenated and aromatic solvents, such as chlorobenzene and chloroform. A combination of characterization methods were employed to gain insight into the film morphology and solar cell performance.