Molecular electrochemical CO2 catalytic reduction to C1 products with 2, 4, 6 and 8 electrons using Co and Fe complexes
a Université de Paris and CNRS, Rue Alice Domon et Léonie Duquet, 10, Paris, France
b Institut Universitaire de France - IUF
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Spring Meeting 2022 (NSM22)
Proceedings of nanoGe Spring Meeting 2022 (NSM22)
#ElectroCat22. Electrocatalysis for the Production of Fuels and Chemicals
Online, Spain, 2022 March 7th - 11th
Organizers: Julio Lloret Fillol and James Durrant
Invited Speaker, Marc Robert, presentation 179
DOI: https://doi.org/10.29363/nanoge.nsm.2022.179
Publication date: 7th February 2022
DOI: https://doi.org/10.29363/nanoge.nsm.2022.179
Publication date: 7th February 2022
Electrochemical reduction of carbon dioxide (CO2) to carbon monoxide (CO) and other C1 products under mild conditions opens a way to produce fuels and chemical feedstock. Molecular catalysts made of Earth-abundant metals may be operated in homogeneous conditions or as supported heterogeneous systems.
Co and Fe complexes demonstrate excellent conversion of CO2 to CO with a selectivity reaching 99 %, in organic solvent as well as in water. By setting proper conditions, we recently discovered that formaldehyde and methanol (Co complex) as well as methane (Fe complex) could be obtained. In other words, CO2 could be reduced with 2, 4, 6 and 8 electrons with molecular catalysts. Our most recent results will be presented.
© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO