Pb-free and Nanocrystal Perovskites for the Development of Solar Cells and LEDs
Iván Mora-Seró a
a Institute of Advanced Materials (INAM), Universitat Jaume I, Av. Sos Baynat, s/n, 12071 Castelló , Spain
Invited Speaker, Iván Mora-Seró, presentation 015
DOI: https://doi.org/10.29363/nanoge.nipho.2023.015
Publication date: 3rd April 2023

Halide perovskite solar cells have revolutionized the photovoltaic field in the last decade. In a decade of intensive research it has been a huge improvement in the performance of these devices, however, the two main drawbacks of this system, the use of hazardous Pb and the long term stability, still to be open questions that have not been fully addressed. Sn-based perovskite solar cells are the devices presenting the highest performance after Pb-based but significantly below them. In addition, Sn-based perovskite solar cells exhibit a long term stability lower than their Pb containing counterparts, making stability their main problem. In this talk, we highlight how the use of proper additives and light soaking for defect engineering can increase significantly the stability of formamidinium tin iodide (FASnI3) solar cells, and discuss about the different mechanism affecting this stability, beyond the oxidation of Sn2+, and how they can be countered. As a second topic of the talk, the use of halide perovskite nanocrystals for the preparation of reproducible perovskite LEDs (PeLEDs) will be analyzed as well as the fabrication of Pb-free LEDs by inkjet printing.

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