Insights into Scalable Inkjet Printing for Perovskite Solar Cells
Florian Mathies a, Katrin Hirselandt a, Oleksandra Shargaieva a, Ulrich W. Paetzold b, Uli Lemmer b, Eva Unger a c
a Young Investigator Group, Hybrid Materials Formation and Scaling, Helmholtz-Zentrum Berlin, Albert-Einstein-Straße, 16, Berlin, Germany
b Light Technology Institute, Karlsruhe Institute of Technology, Karlsruhe, Germany
c Department of Chemistry & NanoLund, Lund University, Sweden, Sweden
NIPHO
Proceedings of nanoGe International Conference on Perovskite Solar Cells, Photonics and Optoelectronics (NIPHO19)
International Conference on Perovskite Thin Film Photovoltaics
Jerusalem, Israel, 2019 February 24th - 27th
Organizers: Lioz Etgar and Kai Zhu
Oral, Florian Mathies, presentation 025
DOI: https://doi.org/10.29363/nanoge.nipho.2019.025
Publication date: 21st November 2018

In this contribution, we address some general considerations to succeed in inkjet printing perovskite solar cells: starting from substrate properties to ink development and technical requirements when utilizing inkjet printing as a technique.

We will point out the importance of substrate modification routines to ensure a good wettability and highly reproducible printing results. Determining the substrate surface energy by means of contact angle measurements enables us to define criteria for the ink development. Intrinsic solvent properties such as surface tension, viscosity, boiling point and solubility but also toxicity define a set of parameters to be considered when developing a printable ink formulation. By controlling the ink formulation, as well as the post-processing parameters, we are able to control the film roughness and thickness, thus changing the crystallization dynamics [1], [2]. Preliminary work on multi-cation perovskite solar cells in combination with a vacuum annealing post-processing step leads to power conversion efficiencies of 15% for an n-i-p solar cell on a sub-cm² cell area size [3]. We now focus on in-situ characterization of perovskite film formation kinetics as a function of precursors composition and process conditions to unveil the role of solution chemistry and intermediate states in determining sample morphology and quality.

The presented insights of this study paves the way for large area, low-cost and high-throughput inkjet-printed perovskites for efficient thin film solar cells.

We gratefully acknowledge financial support of the Initiating and Networking funding of the Helmholtz Association (HYIG of U.W.P. and E.U.) We acknowledge financial support by the German Federal Ministry of Education and Research through Grant 03SF0483 (PeroSol).

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