Bismuth-based perovskite nanocrystals for photoelectrochemical - photocatalytic applications
Roberto Altieri a, Mengjiao Wang a, Teresa Gatti a
a Center for Materials Research (ZfM), Justus Liebig University Giessen, Germany, Ludwigstraße, 23, Gießen, Germany
Materials for Sustainable Development Conference (MATSUS)
Proceedings of Materials for Sustainable Development Conference (MAT-SUS) (NFM22)
#PbFreePero - The potential of lead-free perovskites: synthesis, properties, and applications
Barcelona, Spain, 2022 October 24th - 28th
Organizers: Loreta Muscarella, Eline Hutter and Hendrik Bolink
Poster, Roberto Altieri, 296
Publication date: 11th July 2022

Metal halide perovskites have been widely studied in the fields of optoelectronics, due to their tunable optical and electronic properties. The typical structure, ABX3, involves a large monovalent cation (A) like Cesium or Rubidium, a divalent metal cation (B) (where Pb stands out for the optical properties)[1], and a halogen (X).
A relatively novel application involves the use of dimensionally reduced perovskite nanocrystals (PNCs) in photocatalysis and photoelectrochemistry, where H2 evolution[2] and CO2 reduction[3] have been already demonstrated.
Due to the Pb toxicity and limited stability to standard environmental conditions, research is now focusing on developing lead-free halide perovskites, like the Bi-based vacancy-ordered perovskites (A3B2X9) or the double perovskites (A2B(I)B(III)X6), where Pb2+ is replaced by a combination of +1 and +3 cations (such as Ag+ and Bi3+).
Our work is focusing on the synthesis and characterization of bismuth-based PNCs, where multiple candidates are being studied, such as the Cs3Bi2X9 and Cs2AgBiX6 (X=Cl, Br,I) PNCs, improving their optical properties through metal Ion doping. In addition, we aim at preparing hybrid heterostructures with other low-dimensional materials, such as graphene-based materials, carbon nanotubes, 2D carbon nitrides and 2D transition metal dichalcogenides employing covalent and non-covalent hybridization methods, in order to improve stability and activity in photo(electro)catalysis.
 

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