Effects of TiO2 structure and Co addition as a second metal on Ru‑based catalysts supported on TiO2 for selective hydrogenation of furfural to FA
Weerachon Tolek a, Natdanai Nanthasanti a, Boontida Pongthawornsakun a, Piyasan Praserthdam a, Joongjai Panpranot a
a Center of Excellence on Catalysis and Catalytic Reaction Engineering, Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok 10330, Thailand
Materials for Sustainable Development Conference (MATSUS)
Proceedings of Materials for Sustainable Development Conference (MAT-SUS) (NFM22)
#Suschem- Materials and electrochemistry for sustainable fuels and chemicals
Barcelona, Spain, 2022 October 24th - 28th
Organizers: Marta Costa Figueiredo and Raffaella Buonsanti
Poster, Weerachon Tolek, 286
Publication date: 11th July 2022

The TiO2 supported Ru-based catalysts were prepared with 1.5 wt% Ru and 0–0.8 wt% Co on various TiO2 (anatase, rutile, P-25, and sol–gel TiO2) and studied in the liquid-phase selective hydrogenation of furfural to furfuryl alcohol (FA) under mild conditions (50 °C and 2 MPa H2). The presence of high anatase crystallographic composition on TiO2 support was favorable for enhancing hydrogenation activity, while the strong interaction between Ru and TiO2 (Ru–TiOx sites) was required for promoting the selectivity to FA. The catalytic performances of bimetallic Ru–Co catalysts were improved with increasing Co loading due to the synergistic effect of Ru–Co alloying system together with the strong interaction between Ru and Co as revealed by XPS, H2-TPR, and TEM–EDX results. The enhancement of reducibility of Co oxides in the bimetallic Ru–Co catalysts led to higher hydrogenation activity with the Ru–0.6Co/TiO2 catalyst exhibited the best performances in FA selective hydrogenation of furfural to FA under the reaction conditions used.

The financial supports from the Rachadapisek Sompote Endowment Fund for the Postdoctoral Fellowship,
Chulalongkorn University for W.T., the Research Team Promotional grant from the National Research Council
of Thailand, and the International Research Network (IRN62W0001) and CAT-REAC Industrial Project
RDG6250033 from the Thailand Science Research Council of Thailand are gratefully acknowledged.

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