ROLE of SPACER CATIONS and STUCTURAL DISTORTION in TWO-DIMENSIONAL GERMANIUM HALIDE PEROVSKITES
Rossella Chiara a, Lorenzo Malavasi a, Massimo Boiocchi b, Mauro Coduri a, Marta Morana a, Francesco Fracassi c, Andrea Listorti c, Arup Mahata d, e, Paolo Quadrelli a, Mattia Gaboardi f, Chiara Milanese a, Luca Bindi g, Filippo De Angelis d, e, h, Marinella Striccoli c
a University of Pavia and INSTM, Via Torquato Taramelli, 12, Pavia, Italy
b Centro Grandi Strumenti (CGS), University of Pavia
c Department of Chemistry, University of Bari Aldo Moro, Via Orabona 4, 70126 Bari, Italy
d Computational Laboratory for Hybrid/Organic Photovoltaics (CLHYO), Istituto CNR Di Scienze e Tecnologie Chimiche “Giulio Natta” (CNR-SCITEC), Perugia, Italy
e CompuNet, Istituto Italiano di Tecnologia (IIT), Genova, Genova, Italy
f Elettra-Sincrotrone Trieste S.C.p.A, Strada Statale 14 - km 163,5 in AREA Science Park Basovizza, Trieste, Italy
g Department of Earth Science, University of Firenze
h University of Perugia Department of Chemistry, Biology and Biotechnology, Via dell' Elce di Sotto, 8, Perugia, Italy
#PbFreePero - The potential of lead-free perovskites: synthesis, properties, and applications
Barcelona, Spain, 2022 October 24th - 28th
Organizers: Loreta Muscarella, Eline Hutter and Hendrik Bolink
Poster, Rossella Chiara, 282 Publication date: 11th July 2022
The elucidation of the structure-property correlation in 2D metal halide perovskites is a key issue to understand the dependance of optical properties on structural distortions and to design novel tailored materials. To extend the actual knowledge on this kind of correlation for lead-free materials, we studied four novel 2D germanium bromide perovskites, namely A2GeBr4 with A = phenylethylammonium (PEA), Br-phenylethylammonium (BrPEA), F-phenylethylammonium (FPEA), and benzylammonium (BZA). A dependance of the band gap value and emission characteristics in terms of Stokes shift and peak width has been highlighted and correlated with the octahedral distortion parameters. In addition, by comparing the actual results with previous data on analogous Sn- and Pb-based materials, we observed an intrinsic increased distortion induced by germanium, particularly on the octahedral bon elongation and bon angle variance, and less on the Ge-Br-Ge bond angle. The structural and optical investigation, together with density functional theory simulations, clarified the role of different structural distortion parameters on the optical properties for a series of 2D Ge-containing perovskites, thus providing novel clues for the future design of layered lead-free materials.
nanoGe is a prestigious brand of successful science conferences that are developed along the year in different areas of the world since 2009. Our worldwide conferences cover cutting-edge materials topics like perovskite solar cells, photovoltaics, optoelectronics, solar fuel conversion, surface science, catalysis and two-dimensional materials, among many others.
Previously nanoGe Spring Meeting (NSM) and nanoGe Fall Meeting (NFM), MATSUS is a multiple symposia conference focused on a broad set of topics of advanced materials preparation, their fundamental properties, and their applications, in fields such as renewable energy, photovoltaics, lighting, semiconductor quantum dots, 2-D materials synthesis, charge carriers dynamics, microscopy and spectroscopy semiconductors fundamentals, etc.
International Conference on Hybrid and Organic Photovoltaics (HOPV) is celebrated yearly in May. The main topics are the development, function and modeling of materials and devices for hybrid and organic solar cells. The field is now dominated by perovskite solar cells but also other hybrid technologies, as organic solar cells, quantum dot solar cells, and dye-sensitized solar cells and their integration into devices for photoelectrochemical solar fuel production.
The main topics of the Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics (IPEROP) are discussed every year in Asia-Pacific for gathering the recent advances in the fields of material preparation, modeling and fabrication of perovskite and hybrid and organic materials. Photovoltaic devices are analyzed from fundamental physics and materials properties to a broad set of applications. The conference also covers the developments of perovskite optoelectronics, including light-emitting diodes, lasers, optical devices, nanophotonics, nonlinear optical properties, colloidal nanostructures, photophysics and light-matter coupling.
The International Conference on Perovskite Thin Film Photovoltaics Perovskite Photonics and Optoelectronics (NIPHO) is the best place to hear the latest developments in perovskite solar cells as well as on recent advances in the fields of perovskite light-emitting diodes, lasers, optical devices, nanophotonics, nonlinear optical properties, colloidal nanostructures, photophysics and light-matter coupling.
{{alert.title}}: {{alert.message}}
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info