Chirality Effects and Device Applications from Halide Perovskite Nanocrystals
Joseph Luther a
a National Renewable Energy Laboratory
Materials for Sustainable Development Conference (MATSUS)
Proceedings of Materials for Sustainable Development Conference (MAT-SUS) (NFM22)
#NANOMAT - Advances on the Understanding and Synthesis of Nanomaterials for Photocatalysis and Optoelectronics
Barcelona, Spain, 2022 October 24th - 28th
Organizers: Ludmilla Steier and Daniel Congreve
Invited Speaker, Joseph Luther, presentation 131
DOI: https://doi.org/10.29363/nanoge.nfm.2022.131
Publication date: 11th July 2022

The interconversion of spin, charge and light are being exploited in perovskite materials leading to efficient, new, and unique device concepts. In this talk, we present the design rules which control and explain the mechanism behind chiral transfer from chiral molecules to the HOIS framework in nanostructured embodiments. Chirality can be imparted by chiral ligands attached during synthesis or in post-synthetic ligand exchanges where the chirality can be studied as a function of the nanocrystal size and surface to volume ratio. We show chirality induced properties from halide perovskite nanocrystals of different sizes and in films and then construct multiple types of prototype devices using heterostructure concepts that harness and display these fascinating properties. Some examples include heterostructured LEDs which emit spin-controlled circularly polarized light at room temperature without external magnets, detectors which couple perovskite nanocrystals and carbon nanotubes to detect and discern circularly polarized photons, neuromorphic devices which exhibit persistent photoconduction lasting thousands of seconds beyond a weak light pulse and can also display read/write capabilities.

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info