Strategies to improve the thermal and operational stability of nonfullerene electron acceptors
Derya Baran a, Jianhua Han a, Han Xu a, Juls Bertrandie a
a KAUST Solar Center, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia., Al-Jabriah, Yanbu Arabia Saudita, Yanbu, Saudi Arabia
Materials for Sustainable Development Conference (MATSUS)
Proceedings of Materials for Sustainable Development Conference (MAT-SUS) (NFM22)
#STAPOS - Stability of perovskite and organic solar cells
Barcelona, Spain, 2022 October 24th - 28th
Organizers: Carsten Deibel and Qiong Wang
Invited Speaker, Derya Baran, presentation 095
DOI: https://doi.org/10.29363/nanoge.nfm.2022.095
Publication date: 11th July 2022

Abstract: With the emergence of high-performance nonfullerene electron acceptors (NFA), organic solar cells (OSCs) are particularly appealing as their power conversion efficiencies (PCEs) approaching 20%. Identifying and eliminating the sources of degradation in photovoltaic devices is as crucial as improving the PCEs from the manufacturing and commercialization point of view. In this talk, I will show the strategies we developed to improve the thermal stability of NFA OSCs. Further, I will share the photo degradation behavior of the state-of-the-art NFA OSCs in both indoor and outdoor conditions with multimodal characterizations and in-operando transient electro-optical spectroscopy. Their outdoor operational stability will be assessed under real-world conditions (in a hot and sunny climate in Saudi Arabia). Finally, I present a comparison of indoor and outdoor performance of Y‑series OSCs to demonstrate the importance of materials stability and device longevity for balancing the efficiency, stability, and cost potential of organic photovoltaics in real-world outdoor applications.

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