Proceedings of Materials for Sustainable Development Conference (MAT-SUS) (NFM22)
DOI: https://doi.org/10.29363/nanoge.nfm.2022.038
Publication date: 11th July 2022
OPV efficiency values are moving towards > 20 % for small area cells and > 15 % for large scale modules. With these performance values, OPV is reaching out to applications that are going beyond the typical niche markets. Integration of OPV into functional objects is attractive for building integrated / attached PV, window integrated PV, vehicle integrated PV, textile PV or agri-/horti PV. Most interestingly, all these application scenarios are related to flexibility and light weight. However, besides few demonstrations of ultra-flexible and foldable organic solar cells, the limitations of lightweight OPV that is compatible to mass production are not fully understood.
OPV devices require encapsulation by barrier films to reduce the degradation driven by extrinsic factors, which in turn limits their flexibility and leads to lower specific power values. In this talk, we analyze the packaging requirements for light weight cells and modules. Fully solution-processed and semitransparent organic solar cells performing comparable with conventional indium tin oxide-based devices are processed directly onto different barrier films of varying thicknesses. Direct cell fabrication onto barrier films leads to the elimination of the additional PET substrate and one of the two adhesive layers. In addition to the increase of the specific power to 0.38 W/g, which is more than four times higher than sandwich-encapsulated devices. These organic solar cells exhibit better flexibility and survive 5000 bending cycles with 4.5 mm bending radius, show comparable stability as conventionally encapsulated devices under constant illumination (1 sun) in ambient air for 1000 h. A further step to increase the W/g Figure of Merit is to replace the top laminated barrier by a printed barrier, reducing the weight by another factor of 2. In combination with high performance NFA based composites, these architectures have the potential to overcome the 1 W/gr milestone while still being compatible to roll to roll production.