A new doping strategy of spiro-OMeTAD for instantly efficient and stable perovskite solar cells
Feng Gao a
a Department of Physics Chemistry and Biology Linköping University, 83, 581, Sweden
Materials for Sustainable Development Conference (MATSUS)
Proceedings of Materials for Sustainable Development Conference (MAT-SUS) (NFM22)
#STAPOS - Stability of perovskite and organic solar cells
Barcelona, Spain, 2022 October 24th - 28th
Organizers: Carsten Deibel and Qiong Wang
Invited Speaker, Feng Gao, presentation 013
DOI: https://doi.org/10.29363/nanoge.nfm.2022.013
Publication date: 11th July 2022

Record efficiencies of perovskite solar cells (PSCs) are obtained with spiro-OMeTAD as the hole transport layer. Spiro-OMeTAD is conventionally doped by hygroscopic lithium salts with the assistance of volatile 4-tert-butylpyridine, which, however, brings a time-consuming doping process as well as poor device stability. We successfully develop an instantly efficient and clean doping strategy to replace the conventional spiro-OMeTAD doping. As demonstrated by experimental and theoretical investigations, the radical dopant leads to significant increase of the conductivity through efficient hole polarons generation. The ionic salts can further modulate the work function with negligible effects on the film conductivity, critical for reaching optimal VOC values by a favorable energetic level alignment. Spiro-OMeTAD based on our new doping strategy enables PSCs with a high power conversion efficiency over 25% and an excellent stability against moisture, heat and illumination. Our findings pave the way for achieving PSCs with high efficiencies and excellent stability at the same time. In addition, our doping strategy goes beyond traditional organic semiconductor doping, providing new understanding of organic doping mechanisms which can inspire further optimizations of different optoelectronic devices.

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