Proceedings of nanoGe Fall Meeting 2021 (NFM21)
DOI: https://doi.org/10.29363/nanoge.nfm.2021.255
Publication date: 23rd September 2021
Halide perovskites offer a flexible platform for tuning optoelectronic properties through changes in composition, connectivity, and dimensionality. In prior work, we have explored the dramatic consequences of stoichiometric and substoichiometric substitutions at the octahedral metal site in halide double perovskites. Our work on halide double perovskites has prompted us to explore still more complex perovskites. I will present our recent studies on further increasing the accessible electronic structures of this versatile family of materials by synthesizing mixed-metal perovskites with three different octahedral metal sites and on combining inorganic sublattices of different dimensionality in a single material. These new halide perovskites show unprecedented crystal structures and unusual electronic structures.
This work is supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences (DOE, BES), Division of Materials Sciences and Engineering under Contract DE-AC02-76SF00515.