Proceedings of nanoGe Fall Meeting 2021 (NFM21)
DOI: https://doi.org/10.29363/nanoge.nfm.2021.193
Publication date: 23rd September 2021
Halide double perovskites (A2B’B”X6) have recently shown broadband emission in a single component and attracted various light-emitting device applications. Generally, in these double perovskites, valance and conduction bands are predominately obtained by mono (B’), trivalent (B”) cations, and halogen(X). In this work, we carried out systematically band engineering by distorted octahedra by substituted with mono (Na+), trivalent (In3+) cations, and halide anion (Cl-) and explored their structural, optical properties behavior of the cubic double perovskites Cs2AgBiBr6. In the undoped parent compound, only very weak photoluminescence is observed, but in substitution of Na, In, Cl samples broadband emission peak centered at around 620nm. In addition to this, the substitution of In3+ (25%) and Cl- (100%) showed increased lifetime compared to host material, and comparison of excitation and absorption spectra indicates that all the doped and undoped materials have shown indirect bandgap materials.