Physics of Perovskite Optoelectronic Devices
Wolfgang Tress a
a Institute of Computational Physics, Zurich University of Applied Sciences (ZHAW), 8401 Winterthur (Switzerland)
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Fall Meeting 2021 (NFM21)
#PerFun21. Perovskites I: Solar Cells, Lighting, and Related Optoelectronics
Online, Spain, 2021 October 18th - 22nd
Organizers: Eva Unger and Feng Gao
Invited Speaker, Wolfgang Tress, presentation 188
DOI: https://doi.org/10.29363/nanoge.nfm.2021.188
Publication date: 23rd September 2021

Metal-halide perovskite semiconductors have received tremendous attention in research due to their excellent optoelectronic properties, making them interesting materials for solar cells and light emitting diodes (LEDs). It is fascinating that these perovskites are highly tolerant against electronic defects and at the same time show pronounced ionic conductivity mediated through mobile lattice defects.

In this talk an overview on the effect of mobile ions on solar cells and LEDs operated in pulsed mode is given. It is commented on the consequences, the interplay between electronic and ionic charges has on the interpretation of common characterization techniques such as photoluminescence and impedance spectroscopy.

An example discussed in more detail are lead-free Cs2AgBiBr6 double perovskite solar cells, whose efficiency-limiting processes remain a matter of research.

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