Proceedings of nanoGe Fall Meeting 2021 (NFM21)
DOI: https://doi.org/10.29363/nanoge.nfm.2021.117
Publication date: 23rd September 2021
Halide perovskite semiconductors are extremely promising materials for next-generation photovoltaics and other devices. However, even in spite of their strong performance in devices, these materials exhibit heterogeneity in their chemical, structural, optoelectronic and morphological properties on multiple length scales -- from the macroscale down to the nanoscale. Here, I will present our group's recent work exploring these different length scales of heterogeneity, and how the heterogeneity impacts performance. In particular, I will present multimodal microscopy measurements in which we simultaneously correlate local strucural and chemical properties with local performance. We identify that local, nanoscale trap clusters are responsible for non-radiative power losses but also are the sites that seed degradation -- and these clusters should be the target of elimination to improve device performance and longevity. We show how the local chemical heterogeneity can provide pathways for carriers to avoid these problematic trap clusters, explaining the strong performance of alloyed perovskite compositions. These results highlight the large impact the nanoscale landscape has on performance and device stability -- and, although far from benign, offers a lever to further control device behaviour.