Understanding the Indoor Performance of Organic Solar Cells with Photo-Induced Space Charge in Shallow Defect States
Paula Hartnagel a, Sebastian Beuel b, Thomas Kirchartz a b
a IEK-5 Photovoltaics, Forschungzentrum Jülich, 52425 Jülich, Germany
b Faculty of Engineering and CENIDE, University of Duisburg-Essen, Carl-Benz-Straße, 199, Duisburg, Germany
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Fall Meeting 2021 (NFM21)
#NewOPV21. Advances in Organic Photovoltaics
Online, Spain, 2021 October 18th - 22nd
Organizers: Uli Würfel and Jörg Ackermann
Contributed talk, Paula Hartnagel, presentation 099
DOI: https://doi.org/10.29363/nanoge.nfm.2021.099
Publication date: 23rd September 2021

With the emergence of indoor photovoltaics as a possible application for organic solar cells, new design criteria are developed to facilitate optimum performance under indoor light sources such as light emitting diodes and low light intensities.[1] For instance, a high parallel resistance is more relevant than under 1 sun illumination. Such a high parallel resistance is typically realized by a thick absorber layer to avoid leakage currents.[2] However, organic solar cells with thick active layers are often limited in their performance by space-charge effects caused by doping, asymmetric carrier mobilities or charged trap states.[3, 4] The latter effect is not well understood yet even though shallow defects are commonly found in organic solar cells due to their intrinsic energetic disorder. Thus, we present a theoretical analysis of the influence of photo-induced space charge evoked by energetic disorder on the performance of organic solar cells under indoor conditions.[5] Drift-diffusion simulations enable us to watch space charge build up in shallow defects with increasing light intensity. Also, we observe that the performance of organic solar cells is less sensitive to high levels of energetic disorder under low light operation than under solar irradiation since the density of space charge increases with light intensity. As a consequence, experimentalists should not quickly discard material systems that perform badly under standard test conditions due to energetic disorder as they still could be viable candidates for indoor application.

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