Phase Segregation in Perovskite Nanoparticles and Applications of these Materials in Photocatalytic Processes
Iván Mora-Seró a
a Universitat Jaume I, Institute of Advanced Materials (INAM) - Spain, Avinguda de Vicent Sos Baynat, Castelló de la Plana, Spain
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Fall Meeting19 (NFM19)
#NCFun19. Fundamental Processes in Semiconductor Nanocrystals
Berlin, Germany, 2019 November 3rd - 8th
Organizers: Ivan Infante and Jonathan Owen
Oral, Iván Mora-Seró, presentation 176
DOI: https://doi.org/10.29363/nanoge.nfm.2019.176
Publication date: 18th July 2019

The great success of halide perovskites boosted also the interest on the nanoparticles (NPs) of these materials. Perovskite NP are also generating a huge interest as relative easy preparation methods yield a simple core structure, without need for passivating shells, reach photoluminescence quantum yield (PLQY) higher than 90%.This remarkable PLQY points to low non-radiative recombination and consequently shows excellent rationale for the development of optoelectronic devices. In this talk first the phase segregation into iodine and bromine rich regions under illumination of mixed halide perovskite depending on the crystal size. Phase segregation is not observed for colloidal perovskite nanoparticles with diameter of few tenths nm. However, when these particles are annealed producing grains of bigger size the phase segregation is observed for sizes bigger than 50 nm. In addition, the possibility of use perovskite nanoparticles for photocatalytic applications is also studied for different kinds of inorganic perovskite nanoparticles. 

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