Proceedings of nanoGe Fall Meeting19 (NFM19)
DOI: https://doi.org/10.29363/nanoge.nfm.2019.075
Publication date: 18th July 2019
Magnetic nanoparticles reveal unique magnetic properties which make them relevant for data storage, electronic and mechanical engineering, and biomedical applications[1,2]. With regard to these applications, one of the main aspects of fundamental interest is the magnetic anisotropy and the related magnetization distribution in individual nanoparticles. However, it is challenging to isolate surface-related effects from the effective magnetic anisotropy using macroscopic, integral magnetization methods. A size dependence of surface effects is well established, and non-saturation magnetization behavior in magnetic nanoparticles even at high fields is commonly attributed to surface spin canting or formation of a magnetically dead layer.
Polarized small-angle neutron scattering (SANS) is a versatile technique, which allows investigating the nanoparticle magnetization with spatial resolution[3]. In this presentation, I will give an overview of our studies of ferrite nanoparticles aiming at their intraparticle spatial magnetization distribution as investigated using polarized SANS[4,5]. I will introduce the capabilities of small angle scattering to determine chemical and magnetic nanoparticle morphologies and highlight the different contributions of particle core and surface spin disorder to the macroscopically observed magnetization.
Financial support from the German Research Foundation (DFG: Emmy Noether Grant DI 1788/2-1) is gratefully acknowledged.