Carrier Recombination and Ion Migration: Role of the Contacts.
Emilio Palomares a b
a Institute of Chemical Research of Catalonia (ICIQ), Barcelona Institute of Science and Technology (BIST), Avinguda dels Països Catalans, 16, Tarragona, Spain
b Institució Catalana de Recerca i Estudis Avançats (ICREA), Spain, Passeig Lluis Companys 23, Barcelona, Spain
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Fall Meeting19 (NFM19)
#PERInt19. Interplay of composition, structure and electronic properties in halide-perovskites
Berlin, Germany, 2019 November 3rd - 8th
Organizer: Pablo P. Boix
Invited Speaker, Emilio Palomares, presentation 062
DOI: https://doi.org/10.29363/nanoge.nfm.2019.062
Publication date: 18th July 2019

During my lecture I will present our latest results on the characterization of different type of contacts for perovskite solar cells using advanced photo-induced time resolved techniques. Using PICE (Photo-induced charge extraction), TPV (Photo-induced Transient PhotoVoltage) and other techniques, we have been able to distinguish between capacitive electronic charge, carrier recombination, and ion migration. Moreover, we have been able to stablish the existing relationship between the different intrinsic properties of the perovskite material. Moreover, the results allow us to compare different materials, used as hole transport materials (HTM) and electron transport materians ( ETM), and the relationship between their HOMO and LUMO energy levels, the solar cell efficiency and the charge losses due to interfacial charge recombination processes occurring at the device under illumination. These techniques and the measurements carried out are key to understand the device function and improve further the efficiency and stability on perovskite  based solar cells.

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