Photocatalytic and Photoelectrochemical Degradation of Organic Pollutants with All-Inorganic Metal Halide Perovskite Quantum Dots
Sixto Gimenez Julia a, Drialys Cardenas Moscoso a, Andrés F. Gualdrón-Reyes a b c, Ana Beatriz Ferreira-Vitoreti a d e, Miguel García-Tecedor a, Seon Joon Yoon a, Mauricio Solis de la Fuente e, Iván Mora-Seró a
a Universitat Jaume I, Institute of Advanced Materials (INAM) - Spain, Avinguda de Vicent Sos Baynat, Castelló de la Plana, Spain
b Centro de Investigaciones en Catálisis (CICAT), Universidad Industrial de Santander, Sede UIS Guatiguará, Piedecuesta, Santander, Colombia. C.P. 681011
c Centro de Investigación Científica y Tecnológica en Materiales y Nanociencias (CMN), Universidad Industrial de Santander, Piedecuesta, Santander, Colombia. C.P. 681011
d Department of Natural Science, Federal University of São João del-Rei, 36301-160 São João del-Rei, Brazil
e CAPES Foundation, Ministry of Education of Brazil, Brasília, 70040-020, Brazil
f Lawrence Berkeley National Laboratory, Energy Technologies Area, US, Cyclotron Road, 1, Berkeley, United States
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Fall Meeting 2018 (NFM18)
S1 Solar Fuel 18
Torremolinos, Spain, 2018 October 22nd - 26th
Organizers: Shannon Boettcher and Kevin Sivula
Oral, Sixto Gimenez Julia, presentation 342
DOI: https://doi.org/10.29363/nanoge.nfm.2018.342
Publication date: 6th July 2018

All-Inorganic Halide Perovskite Quantum Dots (QDs) have emerged as a new class of fascinating nanomaterials with outstanding optoelectronic properties, with promise to revolutionize different disciplines like photovoltaics, lasing and emission.[1] In the present talk, we will discuss about the application of these materials for solar-driven environmental remediation. To that aim, it is essential to elucidate the energy levels of CsPbxSn1-xX3 QDs by different techniques and to identify candidate target molecules, which can be oxidized with photogenerated holes in these QDs. As a proof of concept, we demonstrate the efficient photocatalytic and photoelectrochemical oxidation of 2-Mercaptobenzothiazol with CsPbBr3 QDs.

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