Proceedings of nanoGe Fall Meeting 2018 (NFM18)
DOI: https://doi.org/10.29363/nanoge.nfm.2018.335
Publication date: 6th July 2018
A Cobalt-imidazole-based metal organic framework (MOF) deposited over Zr-BiVO4 films was investigated as catalyst for solar water splitting. Photoelectrochemical measures shows an enhanced PEC performance in presence of the MOF, with a 4-fold increase of photocurrent at 1.2 V vs RHE and, more relevant, a photocurrent onset very close to the flatband potential for Zr-BiVO4 (vide infra) due to the significant reduction of surface losses. The determination of the charge separation efficiency (ηcs) and the charge injection efficiency (ηcat) reveals that the MOF catalyst is responsible for a remarkable increase of the charge injection efficiency of the photoanode, up to voltages close to 1.8 V vs RHE, where the high applied electric field vanishes surface recombination. Further mechanistic insights were extracted from impedance spectroscopy measurements in the dark and under illumination for both control and the best BiVO4-MOF electrode.