Proceedings of nanoGe Fall Meeting 2018 (NFM18)
Publication date: 6th July 2018
Nanoparticles showing a localized surface plasmon resonance (LSPR) in the visible part of the electromagnetic spectrum have been intensively researched regarding their potential application in various fields such as surface-enhanced Raman spectroscopy (SERS) or as nanosensors and catalysts [1], [2]. So far, this area of research has been strongly dominated by particles consisting of noble metals like Au and Ag. The presented work will show an evaluation of the extinction properties of alternative materials which have only recently been found to exhibit a LSPR [3]. The range of investigated materials includes highly monodisperse quasi-spherical Ni3S2 nanocrystals and Au-Ni3S2 core-shell nanostructures of different sizes, which will be compared to pure Au nanoparticles regarding their molar extinction coefficient. Our results show that the extinction coefficient of the Ni3S2 nanocrystals is similar to those of Au particles of the same diameter leading to the conclusion that the nickel sulfide material could potentially be used for optical applications instead of the much more expensive noble metal. Additionally, the molar extinction coefficient of the core-shell structures can be varied between the values of the pure materials depending on the shell thickness, resulting in a highly tunable system [4].
The plasmonic nature of the nickel sulfide particles was confirmed by transient absorption spectroscopy measurements and all of the used nanostructures were additionally analyzed via electron microscopy, selected area electron diffraction and x-ray diffraction.
Rasmus Himstedt is grateful to the Hannover School for Nanotechnology (HSN) for financial support. Dominik Hinrichs and Dirk Dorfs thank the Deutsche Forschungsgemeinschaft (DFG, Grant 1580/3-1 and 1580/5-1) and the Volkswagen Foundation (Lower Saxony/Israel cooperation, Grant ZN2916) for funding.
The Laboratory for Nano- and Quantumengineering (LNQE) is acknowledged for providing access to TEM measurement facilities.