Modeling and Interpretation of Small Perturbation Measurements in Perovskite Solar Cells
Juan A. Anta a
a Pablo de Olavide University, Sevilla, Spain, Carretera de Utrera, km. 1, Montequinto, Spain
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Fall Meeting 2018 (NFM18)
S8 Modelling Perovskite Solar Cells from the Microscale to the Macroscale
Torremolinos, Spain, 2018 October 22nd - 26th
Organizers: Alison Walker and Claudio Quarti
Invited Speaker, Juan A. Anta, presentation 171
DOI: https://doi.org/10.29363/nanoge.nfm.2018.171
Publication date: 6th July 2018

Metal halide perovskites are mixed ionic-electronic conductors extremely efficient for making solar cells, due to its strong absorption in the visible and their relatively slow recombination. Processes like transport, recombination, charge accumulation, hysteresis, etc. occur at very different time scales and determine the photovoltaic performance of the solar cell. Small-perturbation, frequency-modulated optoelectronic techniques such as impedance spectroscopy (IS) or intensity-modulated photocurrent spectroscopies (IMPS/IMVS) are especially suited to detect, deconvolute and quantify all these processes.

 

Nowadays, a full understanding of the typical features observed in the IS and IMPS/IMVS spectra in perovskite solar cells is still missing. Hence, it is not clear yet how properties like the magnitude, locus and the nature of the recombination loss can be identified or quantified from the analysis of the data. Besides, low frequency signals, associated to hysteresis phenomena should also be unambiguously assessed in the spectra. In this talk I discuss the interpretation of the spectra and the use of simple models to rationalize the small-perturbation response of the device and its impact on efficiency-determining dynamic processes.

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