Proceedings of nanoGe Fall Meeting 2018 (NFM18)
DOI: https://doi.org/10.29363/nanoge.nfm.2018.153
Publication date: 6th July 2018
Fossil fuels need to be replaced quickly and on a large scale to render our energy system compatible with current greenhouse gas emission targets. The scale of the transition is enormous and makes efficiency a key factor for its feasibility. The required pace of the transition, on the other hand, renders the modification of materials, that are already established in photovoltaics, for use in solar water splitting devices attractive.
In the case of light-driven water splitting, multi-junction absorbers are essential to provide enough photovoltage and -current for efficiencies beyond 10%. Challenges arising from the distribution of the solar spectrum over multiple sub-cells include appropriate internal band alignment, spectral shaping by (metallic) co-catalysts and the electrolyte as well as the reduction of reflection losses. In this talk, I will discuss current developments in the field of high-efficiency, immersed water splitting systems of currently up to 19% solar-to-hydrogen and outline the route towards efficiencies beyond 20%. Furthermore, I will outline the impact of efficiency on the potential of photoelectrochemical systems as a negative emission technology.