Investigating the Influence of Nanostructuring on Photoanode Performance
Shababa Selim a, Laia Francas a, Camilo Mesa a, Andreas Kafizas a, Dongho Lee b, Kyoung-Shin Choi b, James R. Durrant a
a Department of Chemistry, Imperial College London, South Kensington Campus London, London, United Kingdom
b Department of Chemistry, University of Wisconsin–Madison, Madison, WI 53706, USA
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Fall Meeting 2018 (NFM18)
S2 Light Driven Water Splitting
Torremolinos, Spain, 2018 October 22nd - 26th
Organizers: Wolfram Jaegermann and Bernhard Kaiser
Oral, Shababa Selim, presentation 098
DOI: https://doi.org/10.29363/nanoge.nfm.2018.098
Publication date: 6th July 2018

The performance of semiconducting materials as photoanodes is continually optimised overtime. With the aid of nanostructuring, noteworthy performance enhancements for the water oxidation reaction are obtained when coupled with electrocatalysts such as FeOOH/NiOOH and Co-Fe Prussian Blue.1,2 In the longstanding compromise between the light penetration depth and charge diffusion lengths, nanostructuring provides an effective tool. However, it is not often efficacious unless coupled with co-catalyst or in presence of hole scavengers. This highlights the presence of significant surface recombination that is especially critical for kinetically demanding reactions such as the four hole oxidation of water, requiring the accumulation of holes on the surface.

In this talk, we will discuss the structure performance relationship between densely packed and mesoporous structures of bismuth vanadate alongside other n-type materials such as titania and hematite. Using techniques such as transient photocurrent measurements (TPC) and photo induced absorption spectroscopy (PIAS), we can directly probe the influence of porosity and increased surface area on electron transport and photo-catalysis.

 

References:

1         T. W. Kim and K.-S. Choi, Science (80-. )., 2014, 343, 990–994.

2         F. S. Hegner, I. Herraiz-Cardona, D. Cardenas-Morcoso, N. López, J. R. Galán-Mascarós and S. Gimenez, ACS Appl. Mater. Interfaces, 2017, 9, 37671–37681.

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